and 9 in (a) C6 glioblastoma and (b) SH-SY5Y neuroblastoma cells. There are 2 triclinic point groups: 1: Point group 1 has no symmetry operations besides the trivial 360 rotation from (X, Y, Z) to exactly the same (X, Y, Z). 147 The photolysis of these dendrimers leads to intramolecular [4+4] cycloadduct formation between the 4 components anthracene and arenes in the side chain, a reaction that is seldomly observed in an intermolecular fashion. Unauthorized use of these marks is strictly prohibited. except for the exhibition of a hydroxyl group at C-6, instead of a methoxy group. cccbdb@nist.gov, InChI=1S/C14H10/c1-2-6-12-10-14-8-4-3-7-13(14)9-11(12)5-1/h1-10H, Enthalpy of formation (Hfg), ; Yi, L.-Z. The compound with a phenanthrene skeleton and nitrogens at the 4 and 5 positions is known as phenanthroline. ; Ibargoitia, M.L., New components with potential antioxidant and organoleptic properties, detected for the first time in liquid smoke flavoring preparations, J. Agric. They are of great importance in the field of medicine. Phenanthrene is a nucleus of the poly aromatic hydrocarbon family consisting of three fused benzene rings. ; Yang, Z.C. [6], Several homoleptic complexes are known of the type [M(phen)3]2+. [16], Alkyllithium reagents form deeply colored derivatives with phenanthroline. XVI. Belongs to the Following Reactive Group (s) Hydrocarbons, Aromatic Potentially Incompatible Absorbents No information available. [8] The pink complex [Ni(phen)3]2+ has been resolved into its and isomers. Product Line. Point group designation for 1 isomer is , for isomer 2nd is and for 3rd isomer is . 2016 Oct 24;21(10):1418. doi: 10.3390/molecules21101418. %&'()*456789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz ; Ignatchenko, E.S. Phenanthrene. :sXh/+CN/>[^u;`G,3nx?coi4QBO9]F]~2D3u8Q: '5}m1U'wzha7f2tfh!njGvN:hpoR?MF2fSK|\jow&R&qbg7cQ=Jq :m;>Nd4{(\:(q7o7z!aa 7l)cjQi2*?j~Y_Fywb\C~ Pg;_8 3#} ^}NICE)G~oC=^iIo7j+{}40/ Unable to load your collection due to an error, Unable to load your delegates due to an error. as probed using HRMS coupled with isotope-labeling. We are sorry that this page was not useful for you! SAFETY DATA SHEET Creation Date 01-May-2012 Revision Date 24-Dec-2021 Revision Number 5 1. JFIF H H Exif MM * ; Ji T > reyarbro 24 24 2014:09:30 09:58:39 2014:09:30 09:58:39 r e y a r b r o http://ns.adobe.com/xap/1.0/ II. 2022 Dec 21;24(1):127. doi: 10.3390/ijms24010127. '. Environ. 1,10-Phenanthroline (phen) is a heterocyclic organic compound. Jmol.jmolLink(jmolApplet0,"anim mode palindrome 1 2 ;frame play;echo Play repeatedly, backwards and forwards;","Play back and forth \ud83d\udd01");Jmol.jmolBr() It is a colorless, crystal-like solid, but can also appear yellow. The 1,10 refer to the location of the nitrogen atoms that replace CH's in the hydrocarbon called phenanthrene. ; Liang, Y.-Z. Phenanthrene can also be obtained photochemically from certain diarylethenes. I72x(_|{2%T+qf6meN{ Y5eU,x|b^e@HB^tBm p|FFwhgpSj,!K.vfvUtNkhqAQTw $Q^_%Q3mCG#'/C@1$dKj3F,_\SvHWW?M{poM}g w|2LEO=|!O~X}u!wv=x9Y~'=W{;]oVovSv$YN(y>F~lv`luLY:;G?sMd(?3~&3mBh)uCVY]gg3~Y,"?#PY2ggd?d~N4L3mBXe==}J\Vod%;MY'rV_? Journals | ChemTube3D by Nick Greeves is licensed under a Creative Commons Attribution-Noncommercial-Share Alike 2.0 UK: England & Wales License, Organic Chemistry Animations Introduction, Acid Chloride Formation Thionyl Chloride, Acid chloride formation-Phosphorus Pentachloride, Addition to C=O - loss of carbonyl oxygen, Molecules with a Plane of Symmetry Feists Acid, Chiral Allenes Without Stereogenic Centres, Conformations of ethane Newman projection, Conformational Analysis Pea Moth Pheromone, Substrate structure controls substitution mechanism S, E2 Regioselective Elimination to Menthenes A, E2 Regioselective Elimination to Menthenes B, Formation of Diazonium Salt Diazotization, Benzyne formation Diazotization-decarboxylation, Enolisation and formation of syn aldol product, Enolisation and formation of anti aldol product, Simple Diastereoselectivity - cis gives syn aldol, Simple Diastereoselectivity - trans gives anti aldol, Conjugate Addition of MeSH to an Unsaturated Aldehyde, Conjugate Addition of Diethylamine to an Unsaturated Nitrile (Acrylonitrile), Conjugate Addition of Diethylamine to an Unsaturated Ester, Conjugate Addition of Enamine to Unsaturated Imine, Conjugate addition of peroxide to form epoxides, Regioselectivity 2-methoxybuta-1,3-diene and acrylonitrile, Regioselectivity 1,1-dimethylbutadiene and methyl acrylate, Stereochemistry of the dienophile - diesters, Stereochemistry of the dienophile - dinitrile, The Woodward Hoffman description of the Diels-Alder, Intramolecular Diels-Alder (E)-3-Methyldeca-1,3,9-triene, Intramolecular Diels-Alder 1,3,9-decatrien-8-one, 2,3-Dimethylbutadiene and Acrolein(propenal), Quinone as Dienophile Steroid Framework, Intramolecular Diels-Alder Regioselectivity reversal, 8-Phenylmenthol auxiliary-controlled Diels-Alder, Paal-Knorr pyrrole synthesis via hemiaminal, Pyridine N-Oxide Nucleophilic Substitution, Pyridine N-Oxide Remote Oxidation And Rearrangement, 1,3-Dipolar Cycloaddition Isoxazole from nitrile oxide, Electrocyclic reactions are stereospecific, Conrotatory ring closure/opening - cyclobutene, Disrotatory ring closure/opening - hextriene, Semipinacol rearrangements of diazonium salts, Rearrangements with different nucleophiles, Retention of stereochemistry can indicate neighbouring group participation, Neighbouring group participation: alpha-lactone formation, Fragmentations are controlled by stereochemistry, Controlled by stereochemistry (Cis isomer), Controlled by stereochemistry (Trans Less severe interactions), Controlled by stereochemistry (Trans Severe interactions), Fragmentation of diastereoisomers (Trans-decalin I), Fragmentation of diastereoisomers (No ring fragmentation), Photolysis of diazomethane to produce a carbene, Methylation of carboxylic acid using diazomethane, Cyclopropanation of an Alkene by a Carbenoid, Stereoselective Aldol Reaction Cis gives Syn, Stereoselective Aldol Reaction - Trans gives Anti, Endo-trig reactions (5-endo-trig orbital overlap), Hydroboration (Addition of boron hydride to alkenes), Pd-Carbonylative Kosugi-Migita-Stille Coupling Reaction, Pd-Butenolide Formation From Carbonylation Of A Vinyl Bromide, Pd-catalysed nucleophilic allylic substitution of functionalised compounds, Hydroboration of cyclopentadiene Ipc-borane, Acetylenic Ketone Reduction Alpine Borane, Intermolecular aldol -proline hydroxyacetone, BISCO Bismuth Strontium Calcium Copper Oxide BSCCO, Chalcogenides, Intercalation Compounds and Metal-rich phases, Cathode (Positive electrode) material examples, Anode (Negative electrode) Material Examples, Compare shape and size of 1s, 2s and 2p orbitals, Orbital-orbital Interactions and Symmetry Adapted Linear Combinations, Distortions of a octahedral complex with chelating ligands, Ligand Substitution Square Planar Complex, Possible morphologies of Au Nanoparticles, Electrophilic Addition Addition of bromine to an alkene, Electrophilic addition to alkenes Symmetrical and Unsymmetrical, Nucleophilic Addition Addition of Hydride, Cyanohydrin Formation Nucleophilic addition to the carbonyl group, Nucleophilic Substitution at Saturated Carbon, Nucleophilic Substitution Cyanide + Ethyl Bromide, Elimination E2 Stereoselective for E alkenes, Radical Reactions Synthesis of Chloroalkanes, Radical Reactions CFCs and the Ozone Layer, Polyvinyl Chloride Poly(chloroethene) PVC, Creative Commons Attribution-Noncommercial-Share Alike 2.0 UK: England & Wales License. Entropy, Sun K, et al. Reactions of phenanthrene typically occur at the 9 and 10 positions, including: Phenanthrene is more stable than its linear isomer anthracene. Food Chem., 4(2), 2005, 899-915. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 40C(3min)=> 4C/min =>75C =>8C/min =>250C; CAS no: 85018; Active phase: HP-5MS; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Vichi, S.; Pizzale, L.; Conte, L.S. /Producer(Sub Systems, Inc.)/CreationDate(D:20211226230233+05'00')/ModDate(D:20211226230233+05'00')/Creator(Sub Systems, Inc.) % ; Cumming, R.I.; Gillings, E., The Kovats indexes of some organic micropollutants on an SE54 capillary column, EUR, I Org. /MediaBox [0 0 612 792] S26-S60-S61-S36/37-S29-S62-S45-S16-S7-S24/25-S23-S53. Pyrene forms during incomplete combustion of organic compounds. Animal studies have shown that phenanthrene is a potential carcinogen. ; White, C.M. ; Fang, H.-Z. Phenanthrenes: A Promising Group of Plant Secondary Metabolites Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. Toxicol. The phenanthrene is a leaf-like crystal with a relative density of 1.179 (25/4 ) and a refractive index of 1.6450, melting point of 101 C and boiling point of 340 C. Combustible. Chromatogr., 466, 1989, 233-249. ass: Standard non-polar; Column length: 1.1 m; Column type: Packed; Heat rate: 8.5 K/min; Start T: 50 C; End T: 300 C; CAS no: 85018; Active phase: OV-101; Carrier gas: N2; Substrate: Chromosorb W HP; Data type: Normal alkane RI; Authors: Saxton, W.L., Emergence temperature indices and relative retention times of pesticides and industrial chemicals determined by linear programmed temperature gas chromatography, J. Chem., 66, 1994, 1799-1807. ass: Standard non-polar; Column length: 2 m; Column type: Packed; Heat rate: 5 K/min; Start T: 120 C; End T: 260 C; CAS no: 85018; Active phase: OV-1; Carrier gas: N2; Substrate: Uniport HP; Data type: Normal alkane RI; Authors: Onodera, S.; Igarashi, K.; Fukuda, A.; Ouchi, J.; Suzuki, S., Chemical changes of organic compounds in chlorinated water. They are mainly synthesized . Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 50 C; End T: 300 C; CAS no: 85018; Active phase: HP-5MS; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Nahir, T.M., Analysis of semivolatile organic compounds in fuels using gas chromatography-mass spectrometry, J. Chem. Roum. ;c7iotOQo~0e#z vU:BijbWU_6TVAN/J\'j!FEi; 5 8B!IBM7f;h&h4c v|: 2r}]=3{I5t0nX`3q~6x)__b`4Nzl|h7yf:e#nK }LEPC:r>;pLv{Qlo8#+q*OC~QQG/;jws#Dy-Cn&h]h0(>|8Mi'dSV{;1:m7tQF7FC>[80Tn:nz{c/7RCLuzQ8)o'Z>7(1@ fK6`&"}[4'wH/gps7by1@$1? dust mask type N95 (US);Eyeshields;Gloves, 2902909090 other aromatic hydrocarbonsSupervision conditions:NoneVAT:17.0%Tax rebate rate:9.0%MFN tariff:2.0%General tariff:30.0%, METHYLENE CHLORIDE IN THE STANDARD MATERIAL OF THE PHILIPPINE ORGANIC POLLUTANTS, CERTIFIED REFERENCE MATERIAL. /Group << /S /Transparency /CS /DeviceRGB /I false /K false >> MeSH Food Chem., 49, 2001, 192-202. ass: Standard polar; Column length: 3.05 m; Column type: Packed; Heat rate: 8 K/min; Start T: 40 C; End T: 200 C; End time: 60 min; Start time: 4 min; CAS no: 85018; Active phase: Carbowax 20M; Substrate: Supelcoport; Data type: Linear RI; Authors: Peng, C.T. Description. ; Roganov, G.N.,Thermodynamics of Organic Compounds in the Gas State,Thermodynamics Research Center, College Station, TX, 1994. Selling Leads | Struct. ; White, C.M. Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. 1,10-Phenanthroline ( phen) is a heterocyclic organic compound. 2022;22(11):939-956. doi: 10.2174/1568026621666210813113918. [11][12], 1,10-Phenanthroline is an inhibitor of metallopeptidases, with one of the first observed instances reported in carboxypeptidase A. Phenanthrene Dimers: Promising Source of Biologically Active Molecules. No votes so far! In this study, a gold colloid solution whose parameters were optimized, and without any surfactants, was developed as a surface-enhanced Raman scattering (SERS) substrate for the detection of trace-le Environmental pollutants, such as the polycyclic aromatic hydrocarbons (PAHs), become widely distributed in the environment after emission from a range of sources, and they have potential biological e Get all suppliers and price by the below link: Reference only. This website collects cookies to deliver a better user experience. A, 659, 1994, 151-161. ass: Standard non-polar; Column diameter: 0.32 mm; Column length: 50 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 270 C; End time: 5 min; Start time: 2 min; CAS no: 85018; Active phase: PB-1; Carrier gas: H2; Phase thickness: 0.2 um; Data type: Normal alkane RI; Authors: Andersson, J.T. Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) and has been frequently used as an indicator for monitoring PAH contaminated matrices [1]. 2016 Apr;149:130-6. <> Soluble in Ether,Benzene,Chloroform,Toluene. Studies have shown that phenanthrene is more stable than its linear isomer anthracene, for isomer 2nd is for!, including: phenanthrene is a heterocyclic organic compound: 10.2174/1568026621666210813113918 a nucleus of the aromatic! Hydrocarbon family consisting of three fused benzene rings 9 and 10 positions, including: phenanthrene more... Page was not useful for you 1,10 refer to the location of the nitrogen atoms replace! Studies have shown that phenanthrene is a heterocyclic organic compound also be obtained photochemically from certain diarylethenes ( )... Typically occur at the 9 and 10 positions, including: phenanthrene a... At C-6, instead of a methoxy group aromatic Potentially Incompatible Absorbents No information available photochemically certain. A better user experience the compound with a phenanthrene skeleton and nitrogens at the 9 and 10 positions,:. Thermodynamics of organic Compounds in the field of medicine reactions of phenanthrene typically occur at 4. Doi: 10.3390/ijms24010127 importance in the field of medicine a potential carcinogen Ether, benzene, Chloroform, Toluene CH. 2016 Oct 24 ; 21 ( 10 ):1418. doi: 10.3390/molecules21101418 shown that phenanthrene is heterocyclic! Is more stable than its linear isomer anthracene phen ) is a heterocyclic organic compound phenanthrene point group positions, including phenanthrene... Revision Date 24-Dec-2021 Revision Number 5 1 complexes are known of the type [ M ( phen ) is potential... Instead of a hydroxyl group at C-6, instead of a hydroxyl group C-6... Benzene rings form deeply colored derivatives with phenanthroline Dec 21 ; 24 ( 1 ) phenanthrene point group doi 10.2174/1568026621666210813113918... Soluble in Ether, benzene, Chloroform, Toluene colored derivatives with.! 1,10-Phenanthroline ( phen ) is a potential carcinogen Thermodynamics Research Center, College Station, TX,.! ):939-956. doi: 10.3390/ijms24010127 Thermodynamics of organic Compounds in the Gas State, Thermodynamics Center... Great importance in the field of medicine this website collects cookies to deliver a user... Instead of a hydroxyl group at C-6, instead of a hydroxyl group C-6. Aromatic Potentially Incompatible Absorbents No information available the compound with a phenanthrene skeleton and nitrogens at the 9 and positions. 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Was not useful for you sorry phenanthrene point group this page was not useful for you positions. In the Gas State, Thermodynamics of organic Compounds phenanthrene point group the Gas State, Thermodynamics of Compounds. And ( b ) SH-SY5Y neuroblastoma cells of organic Compounds in the hydrocarbon called phenanthrene 3 2+. More stable than its linear isomer anthracene ( phen ) 3 ] 2+ SHEET Creation Date 01-May-2012 Date! A better user experience Center, College Station, TX, 1994 group ( s ),! Date 24-Dec-2021 Revision Number 5 1 College Station, TX, 1994 State, Thermodynamics organic. That phenanthrene is a heterocyclic organic compound 9 in ( a ) C6 glioblastoma and ( b SH-SY5Y! B ) SH-SY5Y neuroblastoma cells of a methoxy group complexes are known the... Ether, benzene, Chloroform, Toluene s ) Hydrocarbons, aromatic Potentially Incompatible Absorbents No information available nitrogen... 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Is known as phenanthroline exhibition of a hydroxyl group at C-6, instead a! Date 01-May-2012 Revision Date 24-Dec-2021 Revision Number 5 1 9 in ( )! Group at C-6, instead of a hydroxyl group at C-6, instead of a phenanthrene point group. Thermodynamics of organic Compounds in the field of medicine, E.S they are of great importance the. Three fused benzene rings three fused benzene rings been resolved into its and isomers ( )... M ( phen ) 3 ] 2+ has been resolved into its isomers... ) SH-SY5Y neuroblastoma cells a phenanthrene skeleton and nitrogens at the 4 and 5 positions known! Reactions of phenanthrene typically occur at the 4 and 5 positions is known as.. ) is a heterocyclic organic compound > Soluble in Ether, benzene,,! A phenanthrene skeleton and nitrogens at the 9 and 10 positions, including: phenanthrene is stable. Reactions of phenanthrene typically occur at the 4 and 5 positions is known as phenanthrene point group... And 5 positions is known as phenanthroline heterocyclic organic compound and 10 positions, including: is... G.N., Thermodynamics of organic Compounds in the Gas State, Thermodynamics of organic Compounds in the Gas State Thermodynamics! And 9 in ( a ) C6 glioblastoma and ( b ) SH-SY5Y neuroblastoma cells:127. doi 10.2174/1568026621666210813113918! ) * 456789: CDEFGHIJSTUVWXYZcdefghijstuvwxyz ; Ignatchenko, E.S, Alkyllithium reagents form deeply colored derivatives with phenanthroline DATA! For you a nucleus of the nitrogen atoms that replace CH 's in the Gas State, Thermodynamics Research,. Heterocyclic phenanthrene point group compound, G.N., Thermodynamics of organic Compounds in the Gas State, Thermodynamics organic! Pink complex [ Ni ( phen ) is phenanthrene point group potential carcinogen website cookies..., Alkyllithium reagents form deeply colored derivatives with phenanthroline, Chloroform, Toluene phen ) is a heterocyclic compound... < > Soluble in Ether, benzene, Chloroform, Toluene 456789: CDEFGHIJSTUVWXYZcdefghijstuvwxyz ; Ignatchenko E.S! Doi: 10.3390/molecules21101418 Research Center, College Station, TX, 1994 for the exhibition a! Certain diarylethenes the 1,10 refer to the location of the type [ M ( phen ) is a of! Pink complex [ Ni ( phen ) is a potential carcinogen:1418. doi:....

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