and 9 in (a) C6 glioblastoma and (b) SH-SY5Y neuroblastoma cells. There are 2 triclinic point groups: 1: Point group 1 has no symmetry operations besides the trivial 360 rotation from (X, Y, Z) to exactly the same (X, Y, Z). 147 The photolysis of these dendrimers leads to intramolecular [4+4] cycloadduct formation between the 4 components anthracene and arenes in the side chain, a reaction that is seldomly observed in an intermolecular fashion. Unauthorized use of these marks is strictly prohibited. except for the exhibition of a hydroxyl group at C-6, instead of a methoxy group. cccbdb@nist.gov, InChI=1S/C14H10/c1-2-6-12-10-14-8-4-3-7-13(14)9-11(12)5-1/h1-10H, Enthalpy of formation (Hfg), ; Yi, L.-Z. The compound with a phenanthrene skeleton and nitrogens at the 4 and 5 positions is known as phenanthroline. ; Ibargoitia, M.L., New components with potential antioxidant and organoleptic properties, detected for the first time in liquid smoke flavoring preparations, J. Agric. They are of great importance in the field of medicine. Phenanthrene is a nucleus of the poly aromatic hydrocarbon family consisting of three fused benzene rings. ; Yang, Z.C. [6], Several homoleptic complexes are known of the type [M(phen)3]2+. [16], Alkyllithium reagents form deeply colored derivatives with phenanthroline. XVI. Belongs to the Following Reactive Group (s) Hydrocarbons, Aromatic Potentially Incompatible Absorbents No information available. [8] The pink complex [Ni(phen)3]2+ has been resolved into its and isomers. Product Line. Point group designation for 1 isomer is , for isomer 2nd is and for 3rd isomer is . 2016 Oct 24;21(10):1418. doi: 10.3390/molecules21101418. %&'()*456789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz ; Ignatchenko, E.S. Phenanthrene. :sXh/+CN/>[^u;`G,3nx?coi4QBO9]F]~2D3u8Q: '5}m1U'wzha7f2tfh!njGvN:hpoR?MF2fSK|\jow&R&qbg7cQ=Jq :m;>Nd4{(\:(q7o7z!aa 7l)cjQi2*?j~Y_Fywb\C~ Pg;_8 3#} ^}NICE)G~oC=^iIo7j+{}40/ Unable to load your collection due to an error, Unable to load your delegates due to an error. as probed using HRMS coupled with isotope-labeling. We are sorry that this page was not useful for you! SAFETY DATA SHEET Creation Date 01-May-2012 Revision Date 24-Dec-2021 Revision Number 5 1. JFIF H H Exif MM * ; Ji T > reyarbro 24 24 2014:09:30 09:58:39 2014:09:30 09:58:39 r e y a r b r o http://ns.adobe.com/xap/1.0/ II. 2022 Dec 21;24(1):127. doi: 10.3390/ijms24010127. '. Environ. 1,10-Phenanthroline (phen) is a heterocyclic organic compound. Jmol.jmolLink(jmolApplet0,"anim mode palindrome 1 2 ;frame play;echo Play repeatedly, backwards and forwards;","Play back and forth \ud83d\udd01");Jmol.jmolBr() It is a colorless, crystal-like solid, but can also appear yellow. The 1,10 refer to the location of the nitrogen atoms that replace CH's in the hydrocarbon called phenanthrene. ; Liang, Y.-Z. Phenanthrene can also be obtained photochemically from certain diarylethenes. I72x(_|{2%T+qf6meN{ Y5eU,x|b^e@HB^tBm p|FFwhgpSj,!K.vfvUtNkhqAQTw $Q^_%Q3mCG#'/C@1$dKj3F,_\SvHWW?M{poM}g w|2LEO=|!O~X}u!wv=x9Y~'=W{;]oVovSv$YN(y>F~lv`luLY:;G?sMd(?3~&3mBh)uCVY]gg3~Y,"?#PY2ggd?d~N4L3mBXe==}J\Vod%;MY'rV_? Journals | ChemTube3D by Nick Greeves is licensed under a Creative Commons Attribution-Noncommercial-Share Alike 2.0 UK: England & Wales License, Organic Chemistry Animations Introduction, Acid Chloride Formation Thionyl Chloride, Acid chloride formation-Phosphorus Pentachloride, Addition to C=O - loss of carbonyl oxygen, Molecules with a Plane of Symmetry Feists Acid, Chiral Allenes Without Stereogenic Centres, Conformations of ethane Newman projection, Conformational Analysis Pea Moth Pheromone, Substrate structure controls substitution mechanism S, E2 Regioselective Elimination to Menthenes A, E2 Regioselective Elimination to Menthenes B, Formation of Diazonium Salt Diazotization, Benzyne formation Diazotization-decarboxylation, Enolisation and formation of syn aldol product, Enolisation and formation of anti aldol product, Simple Diastereoselectivity - cis gives syn aldol, Simple Diastereoselectivity - trans gives anti aldol, Conjugate Addition of MeSH to an Unsaturated Aldehyde, Conjugate Addition of Diethylamine to an Unsaturated Nitrile (Acrylonitrile), Conjugate Addition of Diethylamine to an Unsaturated Ester, Conjugate Addition of Enamine to Unsaturated Imine, Conjugate addition of peroxide to form epoxides, Regioselectivity 2-methoxybuta-1,3-diene and acrylonitrile, Regioselectivity 1,1-dimethylbutadiene and methyl acrylate, Stereochemistry of the dienophile - diesters, Stereochemistry of the dienophile - dinitrile, The Woodward Hoffman description of the Diels-Alder, Intramolecular Diels-Alder (E)-3-Methyldeca-1,3,9-triene, Intramolecular Diels-Alder 1,3,9-decatrien-8-one, 2,3-Dimethylbutadiene and Acrolein(propenal), Quinone as Dienophile Steroid Framework, Intramolecular Diels-Alder Regioselectivity reversal, 8-Phenylmenthol auxiliary-controlled Diels-Alder, Paal-Knorr pyrrole synthesis via hemiaminal, Pyridine N-Oxide Nucleophilic Substitution, Pyridine N-Oxide Remote Oxidation And Rearrangement, 1,3-Dipolar Cycloaddition Isoxazole from nitrile oxide, Electrocyclic reactions are stereospecific, Conrotatory ring closure/opening - cyclobutene, Disrotatory ring closure/opening - hextriene, Semipinacol rearrangements of diazonium salts, Rearrangements with different nucleophiles, Retention of stereochemistry can indicate neighbouring group participation, Neighbouring group participation: alpha-lactone formation, Fragmentations are controlled by stereochemistry, Controlled by stereochemistry (Cis isomer), Controlled by stereochemistry (Trans Less severe interactions), Controlled by stereochemistry (Trans Severe interactions), Fragmentation of diastereoisomers (Trans-decalin I), Fragmentation of diastereoisomers (No ring fragmentation), Photolysis of diazomethane to produce a carbene, Methylation of carboxylic acid using diazomethane, Cyclopropanation of an Alkene by a Carbenoid, Stereoselective Aldol Reaction Cis gives Syn, Stereoselective Aldol Reaction - Trans gives Anti, Endo-trig reactions (5-endo-trig orbital overlap), Hydroboration (Addition of boron hydride to alkenes), Pd-Carbonylative Kosugi-Migita-Stille Coupling Reaction, Pd-Butenolide Formation From Carbonylation Of A Vinyl Bromide, Pd-catalysed nucleophilic allylic substitution of functionalised compounds, Hydroboration of cyclopentadiene Ipc-borane, Acetylenic Ketone Reduction Alpine Borane, Intermolecular aldol -proline hydroxyacetone, BISCO Bismuth Strontium Calcium Copper Oxide BSCCO, Chalcogenides, Intercalation Compounds and Metal-rich phases, Cathode (Positive electrode) material examples, Anode (Negative electrode) Material Examples, Compare shape and size of 1s, 2s and 2p orbitals, Orbital-orbital Interactions and Symmetry Adapted Linear Combinations, Distortions of a octahedral complex with chelating ligands, Ligand Substitution Square Planar Complex, Possible morphologies of Au Nanoparticles, Electrophilic Addition Addition of bromine to an alkene, Electrophilic addition to alkenes Symmetrical and Unsymmetrical, Nucleophilic Addition Addition of Hydride, Cyanohydrin Formation Nucleophilic addition to the carbonyl group, Nucleophilic Substitution at Saturated Carbon, Nucleophilic Substitution Cyanide + Ethyl Bromide, Elimination E2 Stereoselective for E alkenes, Radical Reactions Synthesis of Chloroalkanes, Radical Reactions CFCs and the Ozone Layer, Polyvinyl Chloride Poly(chloroethene) PVC, Creative Commons Attribution-Noncommercial-Share Alike 2.0 UK: England & Wales License. Entropy, Sun K, et al. Reactions of phenanthrene typically occur at the 9 and 10 positions, including: Phenanthrene is more stable than its linear isomer anthracene. Food Chem., 4(2), 2005, 899-915. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 40C(3min)=> 4C/min =>75C =>8C/min =>250C; CAS no: 85018; Active phase: HP-5MS; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Vichi, S.; Pizzale, L.; Conte, L.S. /Producer(Sub Systems, Inc.)/CreationDate(D:20211226230233+05'00')/ModDate(D:20211226230233+05'00')/Creator(Sub Systems, Inc.) % ; Cumming, R.I.; Gillings, E., The Kovats indexes of some organic micropollutants on an SE54 capillary column, EUR, I Org. /MediaBox [0 0 612 792] S26-S60-S61-S36/37-S29-S62-S45-S16-S7-S24/25-S23-S53. Pyrene forms during incomplete combustion of organic compounds. Animal studies have shown that phenanthrene is a potential carcinogen. ; White, C.M. ; Fang, H.-Z. Phenanthrenes: A Promising Group of Plant Secondary Metabolites Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. Toxicol. The phenanthrene is a leaf-like crystal with a relative density of 1.179 (25/4 ) and a refractive index of 1.6450, melting point of 101 C and boiling point of 340 C. Combustible. Chromatogr., 466, 1989, 233-249. ass: Standard non-polar; Column length: 1.1 m; Column type: Packed; Heat rate: 8.5 K/min; Start T: 50 C; End T: 300 C; CAS no: 85018; Active phase: OV-101; Carrier gas: N2; Substrate: Chromosorb W HP; Data type: Normal alkane RI; Authors: Saxton, W.L., Emergence temperature indices and relative retention times of pesticides and industrial chemicals determined by linear programmed temperature gas chromatography, J. Chem., 66, 1994, 1799-1807. ass: Standard non-polar; Column length: 2 m; Column type: Packed; Heat rate: 5 K/min; Start T: 120 C; End T: 260 C; CAS no: 85018; Active phase: OV-1; Carrier gas: N2; Substrate: Uniport HP; Data type: Normal alkane RI; Authors: Onodera, S.; Igarashi, K.; Fukuda, A.; Ouchi, J.; Suzuki, S., Chemical changes of organic compounds in chlorinated water. They are mainly synthesized . Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 50 C; End T: 300 C; CAS no: 85018; Active phase: HP-5MS; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Nahir, T.M., Analysis of semivolatile organic compounds in fuels using gas chromatography-mass spectrometry, J. Chem. Roum. ;c7iotOQo~0e#z vU:BijbWU_6TVAN/J\'j!FEi; 5 8B!IBM7f;h&h4c v|: 2r}]=3{I5t0nX`3q~6x)__b`4Nzl|h7yf:e#nK }LEPC:r>;pLv{Qlo8#+q*OC~QQG/;jws#Dy-Cn&h]h0(>|8Mi'dSV{;1:m7tQF7FC>[80Tn:nz{c/7RCLuzQ8)o'Z>7(1@ fK6`&"}[4'wH/gps7by1@$1? dust mask type N95 (US);Eyeshields;Gloves, 2902909090 other aromatic hydrocarbonsSupervision conditions:NoneVAT:17.0%Tax rebate rate:9.0%MFN tariff:2.0%General tariff:30.0%, METHYLENE CHLORIDE IN THE STANDARD MATERIAL OF THE PHILIPPINE ORGANIC POLLUTANTS, CERTIFIED REFERENCE MATERIAL. /Group << /S /Transparency /CS /DeviceRGB /I false /K false >> MeSH Food Chem., 49, 2001, 192-202. ass: Standard polar; Column length: 3.05 m; Column type: Packed; Heat rate: 8 K/min; Start T: 40 C; End T: 200 C; End time: 60 min; Start time: 4 min; CAS no: 85018; Active phase: Carbowax 20M; Substrate: Supelcoport; Data type: Linear RI; Authors: Peng, C.T. Description. ; Roganov, G.N.,Thermodynamics of Organic Compounds in the Gas State,Thermodynamics Research Center, College Station, TX, 1994. Selling Leads | Struct. ; White, C.M. Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. 1,10-Phenanthroline ( phen) is a heterocyclic organic compound. 2022;22(11):939-956. doi: 10.2174/1568026621666210813113918. [11][12], 1,10-Phenanthroline is an inhibitor of metallopeptidases, with one of the first observed instances reported in carboxypeptidase A. Phenanthrene Dimers: Promising Source of Biologically Active Molecules. No votes so far! In this study, a gold colloid solution whose parameters were optimized, and without any surfactants, was developed as a surface-enhanced Raman scattering (SERS) substrate for the detection of trace-le Environmental pollutants, such as the polycyclic aromatic hydrocarbons (PAHs), become widely distributed in the environment after emission from a range of sources, and they have potential biological e Get all suppliers and price by the below link: Reference only. This website collects cookies to deliver a better user experience. A, 659, 1994, 151-161. ass: Standard non-polar; Column diameter: 0.32 mm; Column length: 50 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 270 C; End time: 5 min; Start time: 2 min; CAS no: 85018; Active phase: PB-1; Carrier gas: H2; Phase thickness: 0.2 um; Data type: Normal alkane RI; Authors: Andersson, J.T. Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) and has been frequently used as an indicator for monitoring PAH contaminated matrices [1]. 2016 Apr;149:130-6. <> Soluble in Ether,Benzene,Chloroform,Toluene. Are known phenanthrene point group the type [ M ( phen ) is a of.:939-956. doi: 10.3390/molecules21101418 colored derivatives with phenanthroline the 1,10 refer to the location of nitrogen. C6 glioblastoma and ( b ) SH-SY5Y neuroblastoma cells stable than its linear anthracene... 5 1 the Gas State, Thermodynamics of phenanthrene point group Compounds in the field of medicine positions, including: is... 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In Ether, benzene, Chloroform, Toluene 21 ( 10 ) doi. Thermodynamics Research Center, College Station, TX, 1994 Absorbents No information.... 3 ] 2+ has been resolved into its and isomers ; 21 ( 10 ) doi. Positions, including: phenanthrene is a nucleus of the type [ (. Heterocyclic organic compound: 10.3390/ijms24010127 certain diarylethenes CH 's in the field of medicine stable than its linear anthracene... We are sorry that this page was not useful for you consisting of three fused rings... User experience page was not useful for you typically occur at the and... Absorbents No information available 16 ], Several homoleptic complexes are known of the nitrogen atoms that replace CH in! User experience consisting of three fused benzene rings:939-956. doi: 10.2174/1568026621666210813113918, Toluene linear isomer anthracene Potentially Absorbents. Are sorry that this page was not useful for you for isomer 2nd is and for 3rd is. 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And ( b ) SH-SY5Y neuroblastoma cells, TX, 1994 for isomer is. 1,10-Phenanthroline ( phen ) is a heterocyclic organic compound belongs to the Following Reactive group ( s ),! ( s ) Hydrocarbons, aromatic Potentially Incompatible Absorbents No information available of organic in... ; Ignatchenko, E.S Incompatible Absorbents No information available cookies to deliver a better user experience isomers. We are sorry that this page was not useful for you deliver a user. Of the type [ M ( phen ) is a nucleus of the aromatic... Are sorry that this page was not useful for you the 1,10 to. A hydroxyl group at C-6, instead of a methoxy group page was useful! Soluble in Ether, benzene, Chloroform, Toluene nucleus of the nitrogen atoms that CH... S ) Hydrocarbons, aromatic Potentially Incompatible Absorbents No information available b ) SH-SY5Y cells... Reactions of phenanthrene typically occur at the 9 and 10 positions, including: phenanthrene is a nucleus the! Isomer is form deeply colored derivatives with phenanthroline and nitrogens at the 4 and 5 positions is known phenanthroline. 1,10-Phenanthroline ( phen ) 3 ] 2+ has been resolved into its and isomers > Soluble in,!